Abstract

Review Article

Investigation of Fuel Cells under Transient (Dynamic) Conditions to Improve the Efficiency of Polymer Electrolyte Fuel Cells in Dead-Ended Anode Mode: Review Article

Parsa Rahimi*

Published: 01 May, 2025 | Volume 9 - Issue 1 | Pages: 012-017

Polymer Electrolyte Membrane Fuel Cells (PEMFCs) operating in Dead-Ended Anode (DEA) mode present a promising alternative to traditional flow-through systems by simplifying design and reducing costs. However, their efficiency and durability are challenged by transient phenomena such as water accumulation, nitrogen buildup, and carbon corrosion throughout operation. This review investigates the dynamic behavior of DEA PEMFCs under dynamic operating states, aiming to improve their efficiency. By analyzing purge cycle optimization and transient response characteristics, we identify strategies to mitigate hydrogen loss, maintain voltage stability, and extend stack lifetime. The key findings indicate that precise purge scheduling and effective water management are critical for optimizing performance, with dynamic models providing insights into time-dependent processes. This study underscores the potential of DEA PEMFCs for high-efficiency applications provided transient effects are effectively managed.

Read Full Article HTML DOI: 10.29328/journal.acee.1001075 Cite this Article Read Full Article PDF

References

  1. Wang Y, Chen KS, Mishler J, Cho SC, Adroher XC. A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research. Appl Energy. 2011;88(4):981-1007. Available from: https://doi.org/10.1016/j.apenergy.2010.09.030
  2. Dumercy L, Péra M-C, Glises R, Hissel D, Hamandi S, Badin F, et al. PEFC stack operating in anodic dead end mode. Fuel Cells. 2004;4(5):352-357. Available from: https://doi.org/10.1002/fuce.200400053
  3. Chen J, Siegel JB, Stefanopoulou AG, Waldecker JR. Optimization of purge cycle for dead-ended anode fuel cell operation. Int J Hydrogen Energy. 2013;38(11):5092-5105. Available from: https://websites.umich.edu/~annastef/FuelCellPdf/Chen2013.pdf
  4. Moçotéguy P, Druart F, Bultel Y, Besse S, Rakotondrainibe A. Monodimensional modeling and experimental study of the dynamic behavior of proton exchange membrane fuel cell stack operating in dead-end mode. J Power Sources. 2007;167(2):349–357. Available from: http://philippe.mocoteguy.free.fr/Publis/JPS01.pdf
  5. Manokaran A, Pushpavanam S, Sridhar P, Pitchumani S. Experimental analysis of spatio-temporal behavior of anodic dead-end mode operated polymer electrolyte fuel cell. J Power Sources. 2011;196(23):9931-9938. Available from: https://doi.org/10.1016/j.jpowsour.2011.06.103
  6. Casadei D, Verducci F, Grimaldi A, Croci D, Palmieri A, Bianchi R, et al. Experimental investigation on the effect of channel geometry on performance heterogeneity in hydrogen PEM fuel cell. Int J Hydrogen Energy. 2024;95:1299-1315. Available from: https://doi.org/10.1016/j.ijhydene.2024.08.515
  7. Tsai SW, Chen YS. A mathematical model to study the energy efficiency of a proton. Appl Energy. 2017;188:151-159. Available from: https://doi.org/10.1016/j.apenergy.2016.11.128
  8. Chen YS, Yang CW, Lee JY. Implementation and evaluation for anode purging of a fuel cell based on nitrogen concentration. Appl Energy. 2014;113:1519-1524. Available from: https://ideas.repec.org/a/eee/appene/v113y2014icp1519-1524.html
  9. Yang CW, Chen YS. A mathematical model to study the performance of a proton exchange membrane fuel cell in a dead-ended anode mode. Appl Energy. 2014;130:113-121. Available from: https://ideas.repec.org/a/eee/appene/v130y2014icp113-121.html
  10. Boillot M, Bonnet C, Jatroudakis N, Carre P, Didierjean S, Lapicque F. Effect of gas dilution on PEM fuel cell performance and impedance response. Fuel Cells. 2006;6(1):31-37. Available from: https://doi.org/10.1002/fuce.200500101
  11. Yang Y, Zhang X, Guo L, Liu H. Different flow fields, operation modes and designs for proton exchange membrane fuel cells with dead-ended anode. Int J Hydrogen Energy. 2018;43(3):1769-1780. Available from: https://doi.org/10.1016/j.ijhydene.2017.10.137
  12. Singer G, Pertl P, Trattner A. Experiments on maximizing hydrogen utilization and efficiency in a PEM fuel cell system. Int J Hydrogen Energy. 2025;106:1158-1166. Available from: https://doi.org/10.1016/j.ijhydene.2025.02.036
  13. Yao J, Wu Z, Wang B, Yang Y, Yang F, Zhang Z, et al. High-stability dead-end anode proton exchange membrane fuel cells by purge optimization. J Power Sources. 2024;595:234062. Available from: https://doi.org/10.1016/j.jpowsour.2024.234062
  14. Mohammadi Taghiabadi M. Analysis of performance degradation in the dead-ended anode proton exchange membrane fuel cell under different load profiles. Fuel. 2024;357(Pt B):129879. Available from: https://doi.org/10.1016/j.fuel.2023.129879
  15. Khan N, Sagheer YA, Wilckens RS. PEFC system reactant gas supply management and anode purging strategy: An experimental approach. Energies. 2022;15(1):288. Available from: https://doi.org/10.3390/en15010288
  16. Pratt JW, Klebanoff LE, Munoz-Ramos K, Akhil AA, Curgus DB, Schenkman BL. Proton exchange membrane fuel cells for electrical power generation on-board commercial airplanes. Appl Energy. 2013;101:776-796. Available from: https://ui.adsabs.harvard.edu/link_gateway/2013ApEn..101..776P/doi:10.1016/j.apenergy.2012.08.003
  17. Oh SD, Kim KY, Oh SB, Kwak HY. Optimal operation of a 1-kW PEMFC-based CHP system for residential applications. Appl Energy. 2012;95:93-101. Available from: https://ideas.repec.org/a/eee/appene/v95y2012icp93-101.html
  18. Liu S, Chen T, Zhang C, Xie Y. Study on the performance of proton exchange membrane fuel cell (PEMFC) with dead-ended anode in gravity environment. Appl Energy. 2020;261:114454. Available from: https://doi.org/10.1016/j.apenergy.2019.114454
  19. Cao Y, El-Shorbagy MA, Dahari M, Cao DN, ElSayed MTE, Huynh PH, et al. Examining the relationship between gas channel dimensions of a polymer electrolyte membrane fuel cell with two-phase flow dynamics in a flooding situation using the volume of fluid method. Energy Rep. 2022;8:9420-9430. Available from: https://doi.org/10.1016/j.egyr.2022.07.048
  20. Ramesh P, Duttagupta SP. Effect of channel dimensions on micro PEM fuel cell performance using 3D modeling. Int J Renew Energy Res. 2013;3(2). Available from: https://dergipark.org.tr/en/download/article-file/148347
  21. Siegel JB, McKay DA, Stefanopoulou AG, Hussey DS, Jacobson DL. Measurement of liquid water accumulation in a PEMFC with dead-ended anode. J Electrochem Soc. 2008;155(11):B1168-1178. Available from: http://dx.doi.org/10.1149/1.2976356
  22. Lee Y, Kim B, Kim Y. An experimental study on water transport through the membrane of a PEFC operating in the dead-end mode. Int J Hydrogen Energy. 2009;34(17):7768-7779. Available from: http://dx.doi.org/10.1016/j.ijhydene.2009.07.010

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