Research Article

Ranking of cadmium low amount measurement systems according to economic, environmental, and functional indicators using ELECTRE analytical method

Benyamin Chahkandi, Mohammad Gheibi* and Amir Takhtravan

Published: 08 September, 2021 | Volume 5 - Issue 1 | Pages: 003-006

Cadmium is one of the transition metals, known by the scientific name Cd. One of its main characteristics is the high toxicity, even in very little amounts. Cadmium is often released through industrial effluents, pesticides, chemical fertilizers, and the burning of fossil fuels. Since the presence of cadmium ions in the living organisms’ body, especially humans, can cause serious damage to the liver and pancreas, and also because its role in causing cancer has been proven, measuring very low amounts of this metal is of high importance. In the first step, this study has reviewed and analyzed common laboratory methods for measuring small amounts of cadmium. Then, according to economic, environmental, feasibility, speed, and accuracy factors, all available methods were evaluated using the ELECTRE technique. The results showed that the extraction methods using Dowex Optipore V-493 resin and extraction system in Triton X-114 surfactant, placed in the first and second positions.

Read Full Article HTML DOI: 10.29328/journal.acee.1001028 Cite this Article Read Full Article PDF


Cadmium; Decomposition methods; Economics; Environment; ELECTRE


  1. Bahlsberg-Pahlsson AM. Toxicity of heavy metals (Zn, Cu, Cd, Pb) to vascular plants. Water Air Soil Pollut. 1989; 47: 287-319.
  2. Kabata-Pendias A, Pendias H. Trace Element in Soil and Plants (3rd edition). CRC Press, Boca Raton, USA. 2001.
  3. John R, Ahmad P, Gadgil K, Sharma S. Effect of cadmium and lead on growth, biochemical parameters and uptake in Lemna polyrrhiza L. Plant Soil Environ. 2008; 54: 262–270.
  4. Zazouli MA, Mohsein Bandpei A, Maleki A, Saberian M, Izanloo H. Determination of cadmium and lead contents in black tea and tea liquor from Iran. Asia J Chem. 2010; 22: 1387-1393.
  5. Li CC, Dang F, Cang L, Zhou DM, Willie JGM. Internal distribution of Cd in lettuce and resulting effects on Cd trophic transfer to the snail: Achatina fulica. Chemosphere. 2015; 135: 123-128. PubMed: https://pubmed.ncbi.nlm.nih.gov/25930053/
  6. Harak T, Kellner V, Ulk J, Jurkova M, Ejka P. Determination of Some Beer Flavors by Stir Bar Sorptive Extraction and Solvent Back Extraction. J Instit Brewing. 2007; 113: 154-158.
  7. Pawliszyn J. Sample Preparation Quo Vadis, Anal Chem. 2003; 75: 2543. PubMed: https://pubmed.ncbi.nlm.nih.gov/12948120/
  8. Jahromi EZ, Bidari A, Assadi Y, Milani Hosseini MR, Jamali MR. Dispersive liquid–liquid microextraction combined with graphite furnace atomic absorption spectrometry: Ultra trace determination of cadmium in water samples. Analytica Chimica Acta. 2007; 585: 305-311.
  9. Dadfarnia S, Haji Shabani AM, Kamranzadeh E, Talanta. 2009; 79: 1061-1065.
  10. Souza Dias FD, Bonsucesso JS, Alves LS, da Silva Filho DC, Costa ACS, et al. Development and optimization of analytical method for the determination of cadmium from mineral water samples by off-line solid phase extraction system using sisal fiber loaded TAR by FAAS. Microchemical J. 2013; 106: 363-367.
  11. Abbasi S, Bahiraei A, Abbasi F. A highly sensitive method for simultaneous determination of ultra trace levels of copper and cadmium in food and water samples with luminol as a chelating agent by adsorptive stripping voltammetry. Food Chem. 2011; 129: 1274-1280. PubMed: https://pubmed.ncbi.nlm.nih.gov/25212367/
  12. Xiang G, Wen S, Wu X, Jiang X, He L, et al. Food Chem. 2012; 132: 532-536.
  13. Li S, Cai S, Hu W, Chen H, Liu H. Ionic liquid-based ultrasound-assisted dispersive liquid–liquid microextraction combined with electrothermal atomic absorption spectrometry for a sensitive determination of cadmium in water samples. Spectrochimica Acta part B. 2009; 64: 666-671.
  14. Melek E, Tuzen M, Soylak M. Flame atomic absorption spectrometric determination of cadmium(II) and lead(II) after their solid phase extraction as dibenzyldithiocarbamate chelates on Dowex Optipore V-493. Analytica Chimica Acta. 2006; 578: 213-219. PubMed: https://pubmed.ncbi.nlm.nih.gov/17723714/
  15. Parham H, Pourreza N, Rahbar N. Solid phase extraction of lead and cadmium using solid sulfur as a new metal extractor prior to determination by flame atomic absorption spectrometry. J Hazardous Materials. 2009; 163: 588–592.
  16. Fang GZ, Tan J, Yan XP. An Ion-Imprinted Functionalized Silica Gel Sorbent Prepared by a Surface Imprinting Technique Combined with a Sol−Gel Process for Selective Solid-Phase Extraction of Cadmium(II). Anal Chem. 2005; 77: 1734-1739. PubMed: https://pubmed.ncbi.nlm.nih.gov/15762579/
  17. Tuzen M, Parlar K, Soylak M. Enrichment/separation of cadmium(II) and lead(II) in environmental samples by solid phase extraction. J Hazardous Materials. 2005; B121: 79–87. PubMed: https://pubmed.ncbi.nlm.nih.gov/15885409/
  18. Maranhao TA, Borges DLG, da Veiga MAMS, Curtius Cloud point extraction for the determination of cadmium and lead in biological samples by graphite furnace atomic absorption spectrometry. Spectrochimica Acta P Part B. 2005; 60: 667-672.
  19. Mortada WI, Hassanien MM, Donia AF, Shokeir AA. Application of Cloud Point Extraction for Cadmium in Biological Samples of Occupationally Exposed Workers: Relation Between Cadmium Exposure and Renal Lesion. Biological Trace Element Res. 2015; 168: 303-310. PubMed: https://pubmed.ncbi.nlm.nih.gov/25998796/
  20. Jafarvand S, Shemirani F. Anal Methods. 2011; 3: 1552-1560.
  21. Zhang C, Wang Y, Chen X, Xia H, Liang P. Determination of Cadmium and Lead in Human Teeth Samples Using Dispersive Liquid-liquid Microextraction and Graphite Furnace Atomic Absorption Spectrometry. J Chin Chem Soc. 2011; 58: 919-924.
  22. Ishizaka A, Nemery P. Multi-Criteria Decision Analysis Methods and Software. John Willey & Sons, Ltd. United Kingdom. 2013.
  23. Sarı, U. Irem, Öztayşi B, Kahraman C. Fuzzy Analytic Hierarch Process Using Type-2 Fuzzy Set: An Application to Warehouse Location Selection. Multicriteria Decision Aid and Artificial Intelligence Links, Theory and Applications. John Willey&Sons, Ltd. United Kingdom 9. 2013.
  24. Triantaphyllou E. Multi-Criteia Decision Making Methods: A Comparative Study. Kluwer Academic Publishers, Boston, USA. 2000.
  25. Triantaphyllou Multi-Criteria DecisionMaking Methods:A Comparative Study. © Springer Science+Business Media Dordrecht 2000.
  26. BIAN KA. Application of Fuzzy AHP and ELECTRE to China Dry Port Location Selection. Asian J Shipping Logistics. 2011; 27:  331–353.


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